CHAPTER 9 CHEMISTRY Doctoral Theses

نویسندگان

  • Rajeev Gupta
  • Ashok K. Prasad
چکیده

The study aims at providing a strategy to synthesize self assembled structures where a coordination complex has been touted as the building block and to accomplish such a strategy, several coordination complexes of pyridineamide based bidenate and tridentate ligands have been used as the building blocks. Further, such building blocks either offer H-bond donor/acceptors groups (phenol, catechol or amide) that form the self-assembled structures or appended pyridine groups that produce discrete {M2 -M1 -M2 2+} heterobimetallic complexes (where M1 3+ = Co or Fe and M2 2+ = Co, Cu Zn, Cd and Hg). Finally presence of Lewis acidic metals in heterobimetallic complexes has been utilized by demonstrating several organic transformation reactions.

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تاریخ انتشار 2013